Structure and Reactivity of (η5-Cyclopentadienyl)(triphenylphosphine)- (undecamethylcyclohexasilyl)nickel(II)-Hexane (2/1)
نویسندگان
چکیده
The nickel cyclohexasilyl complex CpNi(PPh3)Si6Me11 was synthesized from nickelocene, triphenylphosphine, and undecamethylcyclohexasilyl potassium and was fully characterized. It shows a relationship between its Si–Si bond lengths and its reactivity towards oxygen. The cleavage of one cyclopentadienyl ligand from nickelocene by silyl anions in the presence of additional ligands opens a promising new pathway to nickel silyl complexes of the type CpNi(L)-SiR3.
منابع مشابه
High-spin Cyclopentadienyl Complexes, Part 6. σ/π-Rearrangement of Aryl Ligands Connected to Cyclopentadienyliron Fragments
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